Physicomechanical properties of nano-silica effect on geopolymer composites

  • Hisham Mustafa Mohamed Khater Housing and Building National Research Centre (HBNRC), 87 El-Tahreer St., Dokki, Giza, Cairo
Keywords: Nanostructures, sol-gel growth, amorphous materials, composite materials, inorganic compounds

Abstract

Addition of Nano-SiO2 (NS) to geopolymer composites has been studied through measurement of compressive strengths, Fourier Transformer Infra-Red (FTIR) and X-ray diffraction (XRD) analysis. Alumino–silicate materials are coarse aggregate included waste concrete and demolished walls with its cementing binder, cement kiln dust (CKD) used and can possess a pronouncing activation for the geopolymer reaction resulting from the high alkali contents within. Materials prepared at water/binder ratios in a range of 0.30: 0.40 under curing of 40 oC and 100% R.H, while the used activator is sodium hydroxide in the ratio of 2 wt. %. First, CKD is added in the ratio from 10 up to 50 wt., %, and the demolished walls was varied depending on the used CKD content, while using constant ratio of waste concrete (40 wt., %). Second step, depending on the optimum CKD ratio resulted from the first one (40 wt. %), so the control geopolymer mix composed of CKD, demolished walls and waste concrete in the ratio (40:20:40, wt %). NS partially replaced waste concrete by 1 up to 8%. Results indicated that, compressive strengths of geopolymer mixes incorporating NS were obviously higher than those control one, especially at early ages and specially with 3%NS.

References

Aiu, M., Huang, C. P. (2006). The chemistry and physics of nano-cement.Loyola Marymount University, NSF-REU University of Delaware.

ASTM C109M-12 (2012). Standard Test Method for Compressive Strength of Hydraulic Cement Mortars.

Baes, C. F., Mesmer, R. E. The Hydrolysis of Cations, John Willey & Sons, New York, 1976.

Collins, F., Lambert, J., Duan, W. H. (2012). The influences of admixtures on the dispersion, workability, and strength of carbon nanotube–OPC paste mixtures. Cement and Concrete Composites, 34(2), 201-207.

De Vargas, A. S., Dal Molin, D. C., Masuero, Â. B., Vilela, A. C., Castro-Gomes, J., De Gutierrez, R. M. (2014). Strength development of alkali-activated fly ash produced with combined NaOH and Ca (OH)2 activators. Cement and Concrete Composites, 53, 341-349.

Duxson, P., Fernández-Jiménez, A., Provis, J. L., Lukey, G. C., Palomo, A., Van Deventer, J. S. J. (2007-a). Geopolymer technology: the current state of the art. Journal of Materials Science, 42(9), 2917-2933.

Duxson, P., Provis, J. L., Lukey, G. C., Van Deventer, J. S. (2007-b). The role of inorganic polymer technology in the development of ‘green concrete’. Cement and Concrete Research, 37(12), 1590-1597.

Duxson, P. S. W. M., Mallicoat, S. W., Lukey, G. C., Kriven, W. M., Van Deventer, J. S. J. (2007). The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 292(1), 8-20.

Fernández-Jiménez, A., Palomo, A. (2005). Composition and microstructure of alkali activated fly ash binder: effect of the activator. Cement and concrete research, 35(10), 1984-1992.

Fernández-Jiménez, A., Palomo, A., Criado, M. (2006). Alkali activated fly ash binders. A comparative study between sodium and potassium activators. Materiales de Construcción, 56(281), 51-65.

Hajimohammadi, A., Provis, J. L., Van Deventer, J. S. (2008). One-part geopolymer mixes from geothermal silica and sodium aluminate. Industrial & Engineering Chemistry Research, 47(23), 9396-9405.

Khater, H. M. (2010). Influence of metakaolin on resistivity of cement mortar to magnesium chloride solution. Ceramics-Silikáty, 54(4), 325-333.

Khater, H. M. (2012). Effect of calcium on geopolymerization of aluminosilicate wastes. Journal of Materials in Civil Engineering, 24(1), 92-101.

Khater, H. M. (2013-a). Effect of cement kiln dust on geopolymer composition and its resistance to sulfate attack. Green Materials, 1(1), 36-46.

Khater, H. M. (2013-b). Effect of silica fume on the characterization of the geopolymer materials. International Journal of Advanced Structural Engineering (IJASE), 5(1), 1-10.

Li, H., Xiao, H. G., Ou, J. P. (2004). A study on mechanical and pressure-sensitive properties of cement mortar with nanophase materials. Cement and Concrete research, 34(3), 435-438.

Li, H., Xiao, H. G., Yuan, J., Ou, J. (2004). Microstructure of cement mortar with nano-particles. Composites Part B: Engineering, 35(2), 185-189.

Lodeiro, I. G., Fernández-Jimenez, A., Palomo, A., Macphee, D. E. (2010). Effect on fresh CSH gels of the simultaneous addition of alkali and aluminium. Cement and Concrete Research, 40(1), 27-32.

McCormick, A. V., Bell, A. T. (1989). The solution chemistry of zeolite precursors. Catalysis Reviews—Science and Engineering, 31(1-2), 97-127.

Mitchell, D. R. G., Hinczak, I., Day, R. A. (1998). Interaction of silica fume with calcium hydroxide solutions and hydrated cement pastes. Cement and Concrete Research, 28(11), 1571-1584.

Panias, D., Giannopoulou, I. P., Perraki, T. (2007). Effect of synthesis parameters on the mechanical properties of fly ash-based geopolymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 301(1), 246-254.

Papadakis, V. G. (1999). Experimental investigation and theoretical modeling of silica fume activity in concrete. Cement and Concrete Research, 29(1), 79-86.

Phair, J. W., Van Deventer, J. S. J. (2001). Effect of silicate activator pH on the leaching and material characteristics of waste-based inorganic polymers. Minerals Engineering, 14(3), 289-304.

Provis, J. L. (2009). Activating solution chemistry for geopolymers. Geopolymers: Structures, Processing, Properties and Industrial Applications, Wood head Publishing, Abingdon UK, pp: 50-71.

Richardson, I. G. (2000). The nature of the hydration products in hardened cement pastes. Cement and Concrete Composites, 22(2), 97-113.

Saikia, N., Usami, A., Kato, S., Kojima, T. (2004). Hydration behaviour of ecocement in presence of metakaolin. Resource Progressing Journal, 51(1), 35-41.

Senff, L., Hotza, D., Repette, W. L., Ferreira, V. M., Labrincha, J. A. (2010). Effect of nanosilica and microsilica on microstructure and hardened properties of cement pastes and mortars. Advances in Applied Ceramics, 109(2), 104-110.

Taylor, H. F. W. (1993). Nanostructure of C-S-H: Current status. Advanced cement based materials, 1(1), 38-46.

Van Jaarsveld, J. G. S., Van Deventer, J. S. J. (1999). Effect of the alkali metal activator on the properties of fly ash-based geopolymers. Industrial & Engineering Chemistry Research, 38(10), 3932-3941.

Yang, K. H., Song, J. K. (2009). Workability loss and compressive strength development of cementless mortars activated by combination of sodium silicate and sodium hydroxide. Journal of Materials in Civil Engineering, 21(3), 119-127.

Yang, K. H., Song, J. K., Ashour, A. F., Lee, E. T. (2008). Properties of cementless mortars activated by sodium silicate. Construction and Building Materials, 22(9), 1981-1989.

Zhang, X., Chang, W., Zhang, T., Ong, C. K. (2000). Nanostructure of calcium silicate hydrate gels in cement paste. Journal of the American Ceramic Society, 83(10), 2600-2604.

Published
2016-05-03
How to Cite
Khater, H. M. M. (2016). Physicomechanical properties of nano-silica effect on geopolymer composites. Journal of Building Materials and Structures, 3(1), 1-14. https://doi.org/10.34118/jbms.v3i1.20
Section
Original Articles