Development of Materials Based on PET-Siliceous Sand Composite Aggregates
Abstract
Plastic waste recycling for the development of new building materials, such as cementitious composites, appears to be one of the best solutions to get rid of this type of waste. This operation has many economic and ecological advantages. The present study proposes some solutions for the recovery of plastic waste from PET (polyethylene terephthalate) bottles in order to obtain, after heat treatment at 290 °C followed by step cooling, a light composite material (PET-siliceous sand) with a hardness close to that of natural rock. The structure of the material obtained is characterized first; then the effect of this composite, with different substitution rates of natural aggregate, on the behavior of an industrial screed is studied. Afterwards, some specific recommendations for the uses of this screed, and possibly of the composite itself, are given. Although the main effects of certain polymeric additives on the mechanical properties of mortars are known, the mechanisms that are responsible for these effects are not yet well understood. Techniques such FTIR, XRD, SEM and differential scanning calorimetry (DSC) are analytical tools that can be used for the characterization and expertise of this type of composites, particularly the industrial composite screeds. Results from the present article enabled us to state that the composition of the materials obtained remains qualitatively unchanged and that no chemical interaction was observed between the mineral species and the waste PET lightweight aggregate (WPLA) or the composite itself; in fact, no new compounds were formed. In addition, the differential scanning calorimetry (DSC) technique allowed us to conclude that the addition of WPLA has an influence on cement hydration. The thermo-mechanical characterization of WPLA made it possible to observe an excellent arrangement between the PET and siliceous sand. Therefore, the development of WPLA may be another solution for a number of applications in the field of eco-materials for construction and building.
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